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Photochemical hydroformylation of olefins with rhodium catalysts at elevated pressure

✍ Scribed by Alfons Saus; Tuyet Nhu Phu; Manfred J. Mirbach; Marlis F. Mirbach

Book ID
103691872
Publisher
Elsevier Science
Year
1983
Weight
521 KB
Volume
18
Category
Article
ISSN
0304-5102

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πŸ“œ SIMILAR VOLUMES

Hydroformylation of Internal Olefins to
Hydroformylation of Internal Olefins to Linear Aldehydes with Novel Rhodium Catalysts
✍ Lars A. van der Veen; Paul C. J. Kamer; Piet W. N. M. van Leeuwen πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 105 KB πŸ‘ 2 views

Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119Β°, respectively, are suited for this.

Effect of phosphorus ligands on the hydr
Effect of phosphorus ligands on the hydroformylation of olefins over rhodium catalysts under atmospheric pressure
✍ Wanzhi Chen; Shijian Liao; Yun Xu πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 525 KB

## Abstract The hydroformylation of olefins over rhodium catalysts, with phosphorus ligands added in situ, has been studied under atmospheric pressure. In the case of the Rh~4~(CO)~12~ cluster, the phosphine‐modified catalyst exhibits very high activity, but there is a decay of catalyst activity wi