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Photochemical decomposition of N-nitrosamines

✍ Scribed by Edward M. Burgess; J.M. Lavanish

Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
283 KB
Volume
5
Category
Article
ISSN
0040-4039

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✦ Synopsis

A search for further synthetically useful reactions involving substitution of a saturated oarbon atom through intramolecular hydrogen abstraction (1) by a photochemically generated radical held in spatial proximity has led us to examine the photochemical decomposition of N-nltrosamlnes. N-Dlbutglnltrosamlne when Irradiated neat or In hydrocarbon solvents wlth ultraviolet light above 30002 (Hanovla A 550 watt lamp, PYREX filter) was essentially Inert: the

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