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Photochemical conversion of trichloromethyl derivatives of mercury in the solid phase

✍ Scribed by A. K. Mal'tsev; N. D. Kagramanov; O. M. Nefedov

Book ID: 112438001
Publisher: Springer
Year: 1974
Tongue: English
Weight: 479 KB
Volume: 23
Category: Article
ISSN: 1573-9171
DOI: 10.1007/bf00922787

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The rate constant for the recombination of trichloromethyl radicals has been measured in the gasphase photozhlori.lation of chloroform at 344.7OK. The observed value is IO9.62mole-Ilsec-I, much lower than the value -u-edicted by transition state calculations using Gorin's model.