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Rate of recombination of trichloromethyl radicals in the gas phase

✍ Scribed by G.R. De Maré; G.H. Huybrechts

Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
147 KB
Volume
1
Category
Article
ISSN
0009-2614

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✦ Synopsis

The rate constant for the recombination of trichloromethyl radicals has been measured in the gasphase photozhlori.lation of chloroform at 344.7OK. The observed value is IO9.62mole-Ilsec-I, much lower than the value -u-edicted by transition state calculations using Gorin's model.

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