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Photochemical and thermal ligand exchange in a ruthenium(ii) complex based on a scorpionate terpyridine ligand

✍ Scribed by Schofield, Emma R.; Collin, Jean-Paul; Gruber, Nathalie; Sauvage, Jean-Pierre

Book ID
118016437
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
133 KB
Volume
2
Category
Article
ISSN
1359-7345

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**The first cationic transition metal complex containing a 1,2‐dithiolato ligand**, __(1)__, was generated photochemically from the neutral complex in chlorinated solvents. __(1)__ is stable at low temperature; at room temperature an unusual ligand‐exchange takes place. equation image