Complexation of a Phenanthroline analogue of Tr~ger's Base 2 to Ru(Bpy)22+ units results in the formation of a dinuclear complex 3. The spectroscopic data in absorption and emission indicate that the resulting dinuclear compound 3 behaves as two independent monometallic Ru(II) complexes.
TETRAETHYLPHYROPHOSPHITE AS A BRIDGING LIGAND IN A BIMETALLIC RUTHENIUM(II) - RUTHENIUM(II) COMPLEX
✍ Scribed by Galhiane, Mário S.; Franco, Douglas W.
- Book ID
- 121303698
- Publisher
- Taylor and Francis Group
- Year
- 1984
- Tongue
- English
- Weight
- 311 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0095-8972
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📜 SIMILAR VOLUMES
The structures of bimetallic ruthenium(II)-tuthenium(III) ions with a variety of bridging ligands are considered using molecular orbital methods. These ions may by symmetrical with equivalent metal centers or may be distorted with nonequivalent sites, which in the extreme can be identified as Ru(II)
The complex Ru(i-biq)y, where i-blq IS 2.2'-bls-lsoqumolme, was synrheslzcd and srudxd spec~roscoprully rmd elrctrochemically. The strong luminescence exhibited at 77 R m rigd glasses 15 characterized as a trIplet h~ndsenrcrcd cmssion. It us the first example of hgnd-centered luminescence from a Ru(