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A phenanthroline analogue of Tröger's base as bridging ligand in the synthesis of a bimetallic ruthenium (II) complex

✍ Scribed by O. Van Gijte; A. Tatibouët; M. Demeunynck; J. Lhomme; A. Kirsch-De Mesmaeker

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 218 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00151-2

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✦ Synopsis

Complexation of a Phenanthroline analogue of Tr~ger's Base 2 to Ru(Bpy)22+ units results in the formation of a dinuclear complex 3. The spectroscopic data in absorption and emission indicate that the resulting dinuclear compound 3 behaves as two independent monometallic Ru(II) complexes.

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