✦ LIBER ✦

Resolution of a porphyrin analogue of Tröger's base by making use of ligand binding affinity differences of the enantiomers

✍ Scribed by Paul R. Allen; Joost N.H. Reek; Andrew C. Try; Maxwell J. Crossley

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 255 KB
Volume: 8
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(97)00116-x

No coin nor oath required. For personal study only.

✦ Synopsis

The dizinc(ll) bis-porphyrin TrOger's base analogue 3 can be resolved on a moderate scale by chromatography over a mixed silica-L-histidine benzyl ester medium.

📜 SIMILAR VOLUMES

A phenanthroline analogue of Tröger's ba

A phenanthroline analogue of Tröger's base as bridging ligand in the synthesis of a bimetallic ruthenium (II) complex

✍ O. Van Gijte; A. Tatibouët; M. Demeunynck; J. Lhomme; A. Kirsch-De Mesmaeker 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 218 KB

Complexation of a Phenanthroline analogue of Tr~ger's Base 2 to Ru(Bpy)22+ units results in the formation of a dinuclear complex 3. The spectroscopic data in absorption and emission indicate that the resulting dinuclear compound 3 behaves as two independent monometallic Ru(II) complexes.