Photochemical Formation of and Ligand Exchange in a Cationic Dithiolatonickel Complex

✍ Scribed by Prof. Dr. Arnd Vogler; Dr. Horst Kunkely

• Publisher: John Wiley and Sons
• Year: 1981
• Tongue: English
• Weight: 241 KB
• Volume: 20
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198103861

✦ Synopsis

The first cationic transition metal complex containing a 1,2‐dithiolato ligand, (1), was generated photochemically from the neutral complex in chlorinated solvents. (1) is stable at low temperature; at room temperature an unusual ligand‐exchange takes place.
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