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Photoaddition of Ethyl 2,2-Dimethyl-5-oxo-5,6-dihydro-2H-pyridine-1-carboxylate to 2,3-dimethylbut-2-ene

✍ Scribed by Christophe Jeandon; Ralf Constien; Volker Sinnwell; Paul Margaretha

Publisher: John Wiley and Sons
Year: 1998
Tongue: German
Weight: 248 KB
Volume: 81
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19980810210

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✦ Synopsis

Abstract

On irradiation (350 nm) in the presence of excess 2,3‐dimethylbut‐2‐ene, the newly synthesized title compound 5 affords as main products the unexpected cyclopropylpyrrolidine 10 (50%) and the spiro‐oxetane 9 (25%).

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