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Photochemistry of ethyl 2,3-dihydro-2,2-dimethyl-3-oxo-1H-pyrrole-1-carboxylate

โœ Scribed by Jan Patjens; Paul Margaretha

Publisher
John Wiley and Sons
Year
1989
Tongue
German
Weight
402 KB
Volume
72
Category
Article
ISSN
0018-019X

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๐Ÿ“œ SIMILAR VOLUMES

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## Abstract On acetoneโ€sensitized irradiation the title compounds **3aโ€“c** are converted to 2โ€allylโ€3โ€hydroxyโ€1__H__โ€pyrroleโ€2โ€carboxylates **4** in reasonable yields.

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## Abstract On irradiation (350 nm) in the presence of excess 2,3โ€dimethylbutโ€2โ€ene, the newly synthesized title compound 5 affords as main products the unexpected cyclopropylpyrrolidine 10 (50%) and the spiroโ€oxetane 9 (25%).