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Photo-Friesrearrangement of 2-Naphthylbenzoate

✍ Scribed by V. P. Pathak; T. R. Saini; R. N. Khanna


Publisher
Springer Vienna
Year
1983
Tongue
English
Weight
81 KB
Volume
114
Category
Article
ISSN
0026-9247

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Photo-oxidation of 2-(2-furyl)-1,3-dicar
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A very efficient photo-sensitized oxidation of 2-(2-furyl)-1,3-dicarbonyl compounds 1 afford directly hydroperoxides 2 in stereoselective way. Compounds 2, easily isolated, can be conveniently employed in a selective epoxidation of trisubstituted allylic alcohols by a Sharpless-type procedure.