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Photo-oxidation of 2-(2-furyl)-1,3-dicarbonyl compounds

✍ Scribed by R. Antonioletti; F. Bonadies; S. Pesci; A. Scettri

Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
141 KB
Volume
33
Category
Article
ISSN
0040-4039

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✦ Synopsis

A very efficient photo-sensitized oxidation of 2-(2-furyl)-1,3-dicarbonyl compounds 1 afford directly hydroperoxides 2 in stereoselective way. Compounds 2, easily isolated, can be conveniently employed in a selective epoxidation of trisubstituted allylic alcohols by a Sharpless-type procedure.

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