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Phosphorylation of derivatives of β-dialkyaminocrotonitriles with phosphorus(III) halides

✍ Scribed by Aleksandr N. Kostyuk; Yurii V. Svyaschenko; Bogdan B. Barnych; Dmitriy A. Sibgatulin; Eduard B. Rusanov; Dmitriy M. Volochnyuk

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
123 KB
Volume
20
Category
Article
ISSN
1042-7163

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✦ Synopsis

The reaction of β-dialkylaminocrotontriles with phosphorus(III) halides has been investigated. The basicity of the dialkylamino group influences the phosphorylation markedly, with pyrrolidine being the amine of choice. It was found that a solvent and the ratio of triethylamine play a significant role in phosphorylation. Although chloroand dichlorophosphine derivatives proved impossible to separate as individual compounds; their solutions can be successfully used for further transformations.

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