Phosphorescence of α-diketones from ozone-olefin reactions
✍ Scribed by U. Schurath; H. Güsten; R.-D. Penzhorn
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 641 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0047-2670
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The vibration-rotation bands (hleinel bands) of the ground electronic state of OH have been observed in the chemiluminescent gas phase reactions of ozone with ethylene, propylene, I-butene, cis-2-butene and tetramethytethylene at total pressures of about 3 torr at room temperature. The emitting spec
## Abstract A mechanism for ozone–olefin reactions is developed that is consistent with the recent findings of several investigations. These findings suggest a reaction sequence leading to the production of fewer free radical species than has been assumed in the past. Computer simulations using the