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A new mechanism for the reaction of ozone with olefins

✍ Scribed by Marcia C. Dodge; Robert R. Arnts

Publisher: John Wiley and Sons
Year: 1979
Tongue: English
Weight: 422 KB
Volume: 11
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550110405

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✦ Synopsis

Abstract

A mechanism for ozone–olefin reactions is developed that is consistent with the recent findings of several investigations. These findings suggest a reaction sequence leading to the production of fewer free radical species than has been assumed in the past. Computer simulations using the new mechanism reproduce experimental results obtained from the ozonolysis of propylene in air.

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