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Phosphoranyl Radical Intermediates. Free-Radical Addition of Bromotrichloromethane to an Unsaturated Cyclic Oxyphosphorane

โœ Scribed by Bentrude, Wesley G.


Book ID
126033349
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
246 KB
Volume
87
Category
Article
ISSN
0002-7863

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Free-Radical Initiated Addition of Bromo
โœ Dr. W. J. Farrissey Jr.; Dr. F. P. Recchia; Dr. A. A. R. Sayigh ๐Ÿ“‚ Article ๐Ÿ“… 1966 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 119 KB ๐Ÿ‘ 2 views

unsaturated intermediate (5) reacts with the diphosphine in a second, rapid step, giving an intermediate (4) which forms the chelate with loss of CO.