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Free-Radical Initiated Addition of Bromotrichloromethane to Allyl Isocyanate

✍ Scribed by Dr. W. J. Farrissey Jr.; Dr. F. P. Recchia; Dr. A. A. R. Sayigh

Publisher
John Wiley and Sons
Year
1966
Tongue
English
Weight
119 KB
Volume
5
Category
Article
ISSN
0044-8249

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✦ Synopsis

unsaturated intermediate (5) reacts with the diphosphine in a second, rapid step, giving an intermediate (4) which forms the chelate with loss of CO.

πŸ“œ SIMILAR VOLUMES

Thermally Initiated Free-Radical Chain A
Thermally Initiated Free-Radical Chain Addition of Alkanes to Alkynes, II. Kinetics of the Addition of Cyclohexane to Phenylethyne under Supercritical Fluid Conditions
✍ Metzger, JΓΌrgen O. ;Bangert, Fritz πŸ“‚ Article πŸ“… 1994 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 253 KB

The kinetics of the addition of cyclohexane (2) to phenylethyne ( 1 ) proceeding via 2-cyclohexyl-1-phenylethenyl radical(3) to give 1-cyclohexyl-2-phenylethene (4) was investigated in the temperature range from 260 to 340Β°C. The radical chain is initiated by a bimolecular reaction of cyclohe-xane w