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Phosphonamide stabilized allylic carbanions. New homoenolate anion equivalents

โœ Scribed by Evans, David A.; Takacs, James M.; Hurst, Kenneth M.


Book ID
118053644
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
1012 KB
Volume
101
Category
Article
ISSN
0002-7863

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Stabilized carbanions by alkyllithium-in
โœ John P. Gilday; Leo A. Paquette ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 191 KB

Intermediate dianions formed by nucleophilic attack of methyllithium on a-phenyl or a-phenylthio carboxylate salts fragment in highly coordinating solvents to produce stabilized carbanions. Once formed, these anions may be conveniently functionalized with various electrophilic reagents.