𝔖 Bobbio Scriptorium
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Reactions of allylpyrrolidine carbanions with electrophiles. A new homoenolate equivalent

✍ Scribed by Stephen F. Martin; T. DuPriest

Book ID
104235689
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
207 KB
Volume
18
Category
Article
ISSN
0040-4039

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✦ Synopsis

Although the ally1 anions of a variety of 3-heterosubstituted propenes n such as ally1 ethers (1, X = OR, OSiR3),' ally1 thioethers

πŸ“œ SIMILAR VOLUMES

Cu(I)-assisted carbonξ—Έcarbon bond formin
Cu(I)-assisted carbonξ—Έcarbon bond forming reactions of Ξ³,Ξ³-dialkoxyallylic zirconium species: a new versatile homoenolate equivalent of propionate
✍ Azusa Sato; Hisanaka Ito; Yusuke Yamaguchi; Takeo Taguchi πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 65 KB

In the presence of CuCN, reaction of g,g-dialkoxyallylic zirconium species 1 with acyl chloride or allylic phosphates proceeded at the a-position of 1 to give alkanoates 3 after aqueous work-up. The ketene dialkylacetal moiety in the coupling products 2 can be used for further bond forming reaction