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Phosphine exchange in carbonylchlorobis(dimethylphenylphosphine)rhodium(I)

✍ Scribed by Fackler, John P.

Book ID
126211168
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
197 KB
Volume
9
Category
Article
ISSN
0020-1669

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trans-Carbonyl­chloro­bis[tris­(penta­fl
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The title compound, trans-[RhCl(C 18 F 15 P) 2 (CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 ( 14) and 2.2993 (14) A ˚, Rh-Cl = 2.3642 (12) A ˚, Rh-C = 1.824 (4) A ˚, C-Rh-Cl = 174.12 (13) , P-Rh-C = 91.73 (13) and 93.71 (1

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trans-Carbonyl­chloro­bis[diphen­yl(4-tol­yl)phosphine]rhodium(I)
✍ Kirsten, Leo ;Steyl, Gideon ;Roodt, Andreas 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 137 KB

The title compound, [RhCl(C~19~H~17~P)~2~(CO)], can be characterized as a Vaska-type complex containing a diphenyl(4-tolyl)phosphine ligand. The rhodium(I) metal centre has a square-planar coordination. The molecule is disordered, with the Rh atom lying on an inversion centre. The most important bon