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Phosphanyl-Amino Complexes of Nickel(II): Synthesis and Structure

✍ Scribed by Laura Crociani; Francesco Tisato; Fiorenzo Refosco; Giuliano Bandoli; Benedetto Corain


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
452 KB
Volume
1998
Category
Article
ISSN
1434-1948

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✦ Synopsis


New neutral pentacoordinate nickel(II) complexes of the type have been synthesized and characterized both in the solid state and in solution. Interesting X-ray structural data have

been collected for each class of compounds, which show, inter alia, that the pentacoordinate neutral complexes can be ylphosphanyl)aniline (P ʝ NHMe), N,N-dimethyl-2-(diphenylphosphanyl)aniline (P ʝ NMe 2 )], as well as cationic tetra-isolated in two different molecular forms, namely squarepyramidal or bipyramidal-trigonal. coordinate nickel(II) complexes of the type [NiCl(PR 3 )(P ʝ N)] +


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