Phosphanyl-Amino Complexes of Nickel(II): Synthesis and Structure
β Scribed by Laura Crociani; Francesco Tisato; Fiorenzo Refosco; Giuliano Bandoli; Benedetto Corain
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 452 KB
- Volume
- 1998
- Category
- Article
- ISSN
- 1434-1948
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β¦ Synopsis
New neutral pentacoordinate nickel(II) complexes of the type have been synthesized and characterized both in the solid state and in solution. Interesting X-ray structural data have
been collected for each class of compounds, which show, inter alia, that the pentacoordinate neutral complexes can be ylphosphanyl)aniline (P Κ NHMe), N,N-dimethyl-2-(diphenylphosphanyl)aniline (P Κ NMe 2 )], as well as cationic tetra-isolated in two different molecular forms, namely squarepyramidal or bipyramidal-trigonal. coordinate nickel(II) complexes of the type [NiCl(PR 3 )(P Κ N)] +
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