Molecular and Electronic Structure of (2,2′-Bidipyrrinato)nickel(II) Complexes
✍ Scribed by Martin Bröring; Carsten D. Brandt; Johann Lex; Hans-Ulrich Humpf; Jordi Bley-Escrich; Jean-Paul Gisselbrecht
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 193 KB
- Volume
- 2001
- Category
- Article
- ISSN
- 1434-1948
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Reduction of 2-cyanopyridine by sodium in the presence of 3-hexamethyleneiminylthiosemicarbazide produces 2-pyridineformamide 3-hexamethyleneiminylthiosemicarbazone, HAmhexim. Complexes with nickel(II), copper(II) and palladium(II) have been prepared and the following complexes structurally characte
New neutral pentacoordinate nickel(II) complexes of the type have been synthesized and characterized both in the solid state and in solution. Interesting X-ray structural data have been collected for each class of compounds, which show, inter alia, that the pentacoordinate neutral complexes can be