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Synthesis and Structure of the First Molecular Thulium(II) Complex: [TmI2(MeOCH2CH2OMe)3]

✍ Scribed by Prof. Dr. Mikhail N. Bochkarev; Dr. Igor L. Fedushkin; Anatoly A. Fagin; Tatyana V. Petrovskaya; Dr. Joseph W. Ziller; Randy N. R. Broomhall-Dillard; Prof. Dr. William J. Evans


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
420 KB
Volume
36
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


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Zuwachs bei den Komplexen zweiwertiger 4f‐Elemente Waren bisher Eu^II^‐Yb^II^‐ und Sm^II^‐Komplexe bekannt, so wurde nun erstmals auch ein Tm^II^‐Komplex zugänglich. Die intensiv grüne Titelverbindung wurde durch Reaktion von TmI~3~ mit Tm in Dimethoxyethan hergestellt. Der lichtempfindliche Komplex

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The synthesis and characterisation is reported of new, five-group by transmetallation with MeMgCl or LiCH 2 SiMe 3 . The solid state structure of [Mo(NAr) 2 (OCMe 2 -2-py)(CH 2 SiMe 3 )] (5) coordinate molybdenum(VI) bisimidoaryl complexes [Mo(NAr) 2 (O-N)(R)] [Ar = C 6 H 3 (iPr) 2 -2,6; O-N = 2-has

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