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First Examples of Complexes Containing η1-Bonded Phosphaalkynes—Synthesis and Crystal and Molecular Structure of trans-[Mo(AdCP)2(Et2PCH2CH2PEt2)2] (Ad = adamantyl)

✍ Scribed by Dr. Peter B. Hitchcock; Mohd Jamil Maah; Prof. Dr. John F. Nixon; Dr. Jalal A. Zora; Prof. Dr. G. Jeffery Leigh; Dr. Mohamad Abu Bakar

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 214 KB
Volume: 26
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198704741

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✦ Synopsis

electron spectra in the sequence: assignment, LNDO/S-PERTCI ionization energies [ e q (calculated relative intensities), measured vertical ionization energies [ e q a) for 2,3-dimethylfuran: 'Afx), 8.36 (0.92), 8.22; 'A(rr), 9.87 (0.90), 9.70; 'A(o), 12.43 (0.89). 12.05; b) for 4,5,6,7-tetrahydrobenzofuran: 'A(x), 8.55 (0.93), 8.15; 'Afn), 10.16 (0.91), 9.65; 'A(cs), 11.84 (0.91). 11.09.

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