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Synthesis and Structure of Cyclic Gold(I) Phosphanyl Complexes [{Au(PR2)}n]

โœ Scribed by Diana M. Stefanescu; Holming F. Yuen; David S. Glueck; James A. Golen; Arnold L. Rheingold

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
217 KB
Volume
115
Category
Article
ISSN
0044-8249

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The coordination behaviour of 2,6-disilyl-substituted characterized. The formation of 6 results from a [4 + 2] cycloaddition between one alkynyl group of each phosphinine phosphinines towards gold(I) has been examined. The reaction of the bis(trimethylsilyl)phosphinine 1 with [AuCl(SMe 2 )] gives wi