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Phosphanorbornadienes as Ligands in the Transition Metal-Catalyzed Synthesis of Fine Chemicals

✍ Scribed by Dr. Denis Neibecker; Dr. Régis Réau

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
368 KB
Volume
28
Category
Article
ISSN
0044-8249

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Based on a general modular synthetic scheme, a variety of chiral bidentate P/P-, P/S-, P/N-, and P/Se-ligands is accessible in an efficient divergent manner starting from phenol or naphthol derived backbone systems. A library of 20 selected ligands was tested in the Rh-catalyzed asymmetric hydrobora