Based on a general modular synthetic scheme, a variety of chiral bidentate P/P-, P/S-, P/N-, and P/Se-ligands is accessible in an efficient divergent manner starting from phenol or naphthol derived backbone systems. A library of 20 selected ligands was tested in the Rh-catalyzed asymmetric hydrobora
Identification of Suitable Ligands for a Transition Metal Catalyzed Reaction: Screening of a Modular Ligand Library in the Enantioselective Hydroboration of Styrene.
✍ Scribed by Florian Blume; Saskia Zemolka; thorsten Fey; Remo Kranich; Hans-Guenther Schmalz
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 139 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A library of furanoside phosphite‐phosphoroamidite ligands has been synthesized and screened in the palladium‐catalyzed allylic substitution reactions of several substrate types. These series of ligands can be prepared efficiently from easily accessible D‐xylose and D‐glucose. Their mod
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v