Phosphane Ligands with Enaminoketone Scaffold and their Palladium Complexes
✍ Scribed by Michael Schmidt; Prof. Dr. Jürgen Heck
- Book ID
- 112233493
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- German
- Weight
- 465 KB
- Volume
- 638
- Category
- Article
- ISSN
- 0372-7874
No coin nor oath required. For personal study only.
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## Abstract Symmetrically and unsymmetrically substituted benzimidazolium bromides (1a–d = NHC·HBr) were synthesized, incorporating bulky benzyl and/or methoxyethyl substituents (a: R = pentamethylbenzyl, R′ = 2‐methoxyethyl; b: R = 2,3,5,6‐tetramethylbenzyl, R′ = methoxyethyl; c: R, R′ = pentameth
## Abstract Water‐soluble gold(I) and palladium(II) complexes containing different thiolates and the phosphanes 1,3,5‐triaza‐7‐phosphaadamantane (PTA) and 3,7‐diacetyl‐1,3,7‐triaza‐5‐phosphabicyclo[3.3.1]nonane (DAPTA) are described. The complexes were characterised by spectroscopic techniques incl