Stereospecific Synthesis of Palladium(II) Complexes of Macrocyclic Tetradentate Phosphane Ligands
β Scribed by Dr. Rainer Bartsch; Dr. Sibbele Hietkamp; Dr. Stephen Morton; Prof. Dr. Othmar Stelzer
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 223 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract The crown ether phosphanes PAr\*Ph~2~ (1) and PAr\*~2~R [Ar\* = 3,4β(18βcrownβ6)βphenyl; R = Me (2); R = Ph (3)], prepared from PCl~2~R and Ar\*Li, have been studied. The syntheses and characterization of their oxides (4β6), and their BH~3~ (7β9), PdCl~2~ (10β12), and PtCl~2~ (13β15) co
## Abstract The preparation of a macrocyclic diphosphine ligand 5 incorporating a binaphthyl unit and its Ni^II^ and Pd^II^ complexes, 6 and 7, is described. A complete assignment of ^1^H,β ^13^Cβ, and ^31^PβNMR data on the basis of 2D NMR spectroscopy (^1^H, ^1^Hβ, ^13^C, ^1^Hβ, ^31^P, ^1^Hβ, ^31^