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Phosphaalkynes (Alkylidynephosphines)

✍ Scribed by U. Bergstraesser


Book ID
101975085
Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


πŸ“œ SIMILAR VOLUMES


Hydrostannylation of Phosphaalkynes
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## 1,3-diphosphetes / Homocubanes / Carbonyl complexes The hydrostannylation of phosphaalkynes 8 with tin hydrides hydrides 13 or chloro(organo)tin hydrides 4, respectively. An isolated and characterized by-product of the latter reaction 1 depends on the stoichiometry employed: Thus, the 1,2-dihydr

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In organic chemistry, phosphaalkynes are very good synthons for a broad variety of cycloaddition reactions [5]. Accordingly. they have been used for the synthesis of small-to medium-sized heterocycles. Due to the presence ofboth a PC triple bond and a phosphorus lone pair. phosphaalkynes are also ve