✦ LIBER ✦

Pheromone Synthesis, CXLII. A New Synthesis of (3S,4R)-8-Nonene-3,4-diol, the Key Intermediate for the Synthesis of (+)-endo-Brevicomin

✍ Scribed by Mori, Kenji ;Kiyota, Hiromasa

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 363 KB
Volume: 1992
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.1992199201163

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

(3__S__,4__R__)‐8‐Nonene‐3,4‐diol (2), the key intermediate for the synthesis of the bark beetle pheromone (+)‐endo‐brevicomin (1), has been synthesized in 46% overall yield (10 steps) based on erythritol (6) by employing lipase‐mediated asymmetric acetylation as one of the steps.

📜 SIMILAR VOLUMES

ChemInform Abstract: Simple Synthesis of

ChemInform Abstract: Simple Synthesis of 2-Acetyl-5,8-dimethoxy-3,4-dihydronaphthalene: A Key Intermediate for the Synthesis of 4-Demethoxydaunomycinone.

✍ Subhash P. Chavan; Y. Tripura Subbarao; Chittiboyina Amar Gopal 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

Preparative Synthesis of the Key Interme

Preparative Synthesis of the Key Intermediate, (4R,5R)-3-Benzyloxymethyl-4,5-isopropylidenedioxycyclopent-2-enone for Carbocyclic Nucleosides.

✍ Hyung Ryong Moon; Won Jun Choi; Hea Ok Kim; Lak Shin Jeong 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

ChemInform Abstract: Enantioselective Sy

ChemInform Abstract: Enantioselective Synthesis of 4-(1,4-Dimethoxy-2-naphthyl)butane-1,3R-diol, an Intermediate for the Synthesis of 9-Deoxynanaomycin A.

✍ H. R. MOHAN; A. S. RAO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

ChemInform Abstract: Convenient Synthesi

ChemInform Abstract: Convenient Synthesis of the Key Intermediate for Dihydrocorynantheol and Protoemetinol from the Monoacetate of 4-Cyclopentene-1,3-diol.

✍ Yuichi Kobayashi; Kaori Yagi; Yuki Kaneko 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

Pheromone synthesis, CLXX. A new synthes

Pheromone synthesis, CLXX. A new synthesis of faranal [(3S,4R,6E,10Z)-3,4,7,11-tetramethyl-6,10-tridecadienal], the trail pheromone of the pharaoh's ant,Monomorium pharaonis

✍ Mori, Kenji ;Murata, Noriaki 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 352 KB 👁 1 views

## Abstract Faranal (1), the trail‐following pheromone of the worker of Pharaoh's ant (__Monomorium pharaonis__), was synthesized by the coupling reaction of the iododiene 3 with the chiral building block 8 as the key step. The geometrically pure iododiene 3 was prepared by the zirconocene‐mediated

ChemInform Abstract: Pheromone Synthesis

ChemInform Abstract: Pheromone Synthesis. Part 197. Synthesis of the Enantiomers of 2-sec-Butyl-4,5-dihydrothiazole and (1R,5S,7R)-3,4-Dehydro-exo-brevicomin, Pheromone Components of the Male Mouse, Mus musculus.

✍ Takuya Tashiro; Kenji Mori 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 26 KB 👁 1 views