Phase transitions in Cs5(HSO4)2(H2PO4)3crystal
β Scribed by Grebenev, V. V.; Makarova, I. P.; Ksenofontov, D. A.; Komornikov, V. A.; Dmitricheva, E. V.
- Book ID
- 121603909
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2013
- Tongue
- English
- Weight
- 360 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1063-7745
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π SIMILAR VOLUMES
Two new compounds, Rb 2 (HSO 4 )(H 2 PO 4 ) and Rb 4 (HSO 4 ) 3 (H 2 PO 4 ), were synthesized from aqueous solutions of RbHSO 4 /RbH 2 PO 4 . The compounds were characterized by Xray single crystal analysis and neutron powder di4raction. For Rb 2 (HSO 4 )(H 2 PO 4 ), room temperature and a low tempe
The structure of the new protonic conductor, -Cs 3 (HSO 4 ) 2 (H 2Ψx (P 1Ψx , S x )O 4 ) (with a superprotonic transition at 125Β°C), has been determined by single-crystal X-ray diffraction methods. Structural features of this and the related compound, -Cs 3 (HSO 4 ) 2 (H 2 PO 4 ), have been further