Superprotonic conductivity in Cs3(HSO4)2(H2PO4)
β Scribed by Sossina M. Haile; Gisela Lentz; Klaus-Dieter Kreuer; Joachim Maier
- Book ID
- 103575837
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 606 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0167-2738
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π SIMILAR VOLUMES
Investigations of the system CsHSO -CsH PO led to discovery of the new compound, b-Cs (HSO ) (H (P,S)O ), with 4 2 4 3 4 2 x 4 a superprotonic phase transition at 1258C. The room temperature structure of b-Cs (HSO ) (H (P,S)O ) is related to that of 3 4 2 x 4 a -Cs (HSO ) (H PO ) and that of CsHSO -
The structure of the new protonic conductor, -Cs 3 (HSO 4 ) 2 (H 2Ψx (P 1Ψx , S x )O 4 ) (with a superprotonic transition at 125Β°C), has been determined by single-crystal X-ray diffraction methods. Structural features of this and the related compound, -Cs 3 (HSO 4 ) 2 (H 2 PO 4 ), have been further