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pH kinetic studies of the N-demethylation of N,N-dimethylaniline catalyzed by chloroperoxidase

✍ Scribed by Gregory L. Kedderis; Paul F. Hollenberg


Book ID
115706237
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
585 KB
Volume
233
Category
Article
ISSN
0003-9861

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N-demethylation of N,N-dimethylanilines
✍ Dietrich DΓΆpp; JΓΆrg Heufer πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 236 KB

The title reaction proceeds via initial electron transfer (rather than hydrogen atom transfer) from the amine to the photoexcited nitro compound, as demonstrated by methoxy substitution in the substrate and absence of CH3/CD3-discrimination. In 1974, Takami Matsuura and Saito 4) A briefly reported