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The catalytic demethylation of N,N-dimethylaniline-N-oxide by liver microsomes

✍ Scribed by Flora H. Pettit; Daniel M. Ziegler


Book ID
118848317
Publisher
Elsevier Science
Year
1963
Tongue
English
Weight
246 KB
Volume
13
Category
Article
ISSN
0006-291X

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N-demethylation of N,N-dimethylanilines
✍ Dietrich DΓΆpp; JΓΆrg Heufer πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 236 KB

The title reaction proceeds via initial electron transfer (rather than hydrogen atom transfer) from the amine to the photoexcited nitro compound, as demonstrated by methoxy substitution in the substrate and absence of CH3/CD3-discrimination. In 1974, Takami Matsuura and Saito 4) A briefly reported