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N-demethylation of N, N-dimethylanilines effected by excited nitroaromatics

✍ Scribed by D. Döpp; B. Gerding; J. Heufer


Book ID
103488652
Publisher
Elsevier Science
Year
1981
Weight
122 KB
Volume
17
Category
Article
ISSN
0047-2670

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N-demethylation of N,N-dimethylanilines
✍ Dietrich Döpp; Jörg Heufer 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 236 KB

The title reaction proceeds via initial electron transfer (rather than hydrogen atom transfer) from the amine to the photoexcited nitro compound, as demonstrated by methoxy substitution in the substrate and absence of CH3/CD3-discrimination. In 1974, Takami Matsuura and Saito 4) A briefly reported