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Permanganate oxidations. III. Kinetics and mechanisms of the oxidation of furfurals in alkaline media

โœ Scribed by Freeman, Fillmore.; Brant, Jay B.; Hester, Norman B.; Kamego, Albert A.; Kasner, Marc L.; McLaughlin, Thomas G.; Paull, Edward W.


Book ID
126046848
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
578 KB
Volume
35
Category
Article
ISSN
0022-3263

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## Abstract A study was made on permanganate oxidation of olefinic and acetylenic alcohols in aqueous alkali media. Deprotonation constants of alcohols can be calculated from the kinetic data. The rate constant of alkoxide group oxidation exceeded that of the unsaturated bond. For oxidation of the

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The kinetics of the oxidation of 1,10-phenanthroline (1,10-phen) by permanganate were investigated in alkaline medium. A first-order, fractional-order and zero-order dependence of the rate each in [MnO 4 ร€ ], [1,10-phen] and [OH ร€ ], respectively, was observed. The data suggest that the oxidation pr