Permanganate ion oxidations. 14. Kinetics and mechanism of the oxidation of aliphatic aldehydes in acid media
β Scribed by Freeman, Fillmore; Lin, Doris K.; Moore, Gregory R.
- Book ID
- 120429399
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 429 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
The oxidation mechanism of aldehydes with permanganate was studied in acidic and alkaline media on acetaldehyde, propionaldehyde, pivalaldehyde (2,2Π-dimethylpropanal) and chloral substrates. On addition of water to acetaldehyde dissolved in organic solvents the rate increased, and therefore it may
The kinetics of the permanganate-hypophosphite redox reaction has been studied over a wide range of pH by using a stopped-flow technique. It has been found that the reaction leads to the formation of phosphite and orthophosphate, and that the molar ratio of the final products depends on pH. The prop