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Permanganate oxidation of unsaturated alcohols in alkaline media

✍ Scribed by Miklós Jáky; Edit Simon-Trompler

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
130 KB
Volume
34
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

A study was made on permanganate oxidation of olefinic and acetylenic alcohols in aqueous alkali media. Deprotonation constants of alcohols can be calculated from the kinetic data. The rate constant of alkoxide group oxidation exceeded that of the unsaturated bond. For oxidation of the alcoholic group a mechanism based on hydride ion transfer is proposed. © 2002 Wiley Periodicals, Inc. Int J Chem Kinet 34: 561–567, 2002

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