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(Perfluoroalkyl)copper(I) compounds III. Reaction of (perfluoroalkyl)copper(I) compounds with aromatic hydrocarbons

✍ Scribed by P.L. Coe; N.E. Milner

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 387 KB
Volume: 2
Category: Article
ISSN: 0022-1139
DOI: 10.1016/s0022-1139(00)83500-9

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✦ Synopsis

Perfluoroheptyl)copper reacts with aromatic compounds to give the corresponding perfluoroheptyl arenes. Thus benzene and g-xylene yield (perfluoroheptyl)benzene and l-perfluoroheptyl-2,5dimethylbenzene respectively. Toluene and nitrobenzene afford mixtures of o-and p-substituted compounds. Chlorobenzene yields products derived from halogen displacement as well as the expected o/p mixture.

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