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Organocopper species III. The reaction of copper (I) carboxylates with organyl halides

✍ Scribed by Anita H. Lewin; Norman L. Goldberg

Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 104 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)84358-6

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✦ Synopsis

Cuprous carboxylates (acetate, benzoate, pivalate) react with primary, secondary, tertiary, allylic and vinylic halides and tosylates to give the corresponding carboxylate esters. The reaction is executed in refluxing pyridine, under an inert atmosphere and under rigorously anhydrous conditions.

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