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Organocopper intermediates in the exchange reaction of aryl halides with salts of copper(I). The possible role of copper(III)

โœ Scribed by Theodore Cohen; John Wood; Albert G. Dietz Jr.


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
225 KB
Volume
15
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


In 1966, Cohen and Lewin provided evidence that the newly discovered preparation of aryl and vinylbenzoates from aryl and vinyl halides by treatment with cuprous benzoate proceeds by


๐Ÿ“œ SIMILAR VOLUMES


Organocopper species III. The reaction o
โœ Anita H. Lewin; Norman L. Goldberg ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 104 KB

Cuprous carboxylates (acetate, benzoate, pivalate) react with primary, secondary, tertiary, allylic and vinylic halides and tosylates to give the corresponding carboxylate esters. The reaction is executed in refluxing pyridine, under an inert atmosphere and under rigorously anhydrous conditions.