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Remarkable Differences in the Coordination Chemistry of Structurally Related 1,2,4-Triphosphaferrocenes with Copper(I) Halides and Silver(I) Salts

✍ Scribed by Shining Deng; Christoph Schwarzmaier; Manfred Zabel; John F. Nixon; Michael Bodensteiner; Eugenia V. Peresypkina; Gábor Balázs; Manfred Scheer

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
782 KB
Volume
2011
Category
Article
ISSN
1434-1948

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## Abstract Novel copper(I) mixed‐ligand complexes containing 1,2‐bis(diphenylphosphanyl)benzene (dppbz) and 2,4‐dithiouracil (2,4‐dtucH~2~) ligands have been synthesised by addition of the thione ligand to the dinuclear [Cu(μ‐X)(dppbz)]~2~ intermediate in acetonitrile/methanol or acetone solution.