Perchlorodiphenylnitroxide, a remarkably stable, isolable free radical
β Scribed by M. Ballester; J. Riera; C. Onrubia
- Book ID
- 108380095
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 112 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
THE chemical stability of aryl substituted methyl radicals is the result of a compromise between two main factors: steric hindrance to bonding with the trivalent carbon, and delocalization of the lone electron, the former being the predominant. 192
THE formation of perchlorobenzyl (PB) radical has already been postulated in order to account for a number of reactions of perchlorotoluene (I>,l such as its reducto-dimerization to the perchlorostilbenes (II),2 its thermolysis to a mixture of CC14, p erchlorobenzene and perchlorostyrene (III),3'4 a