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Perchlorobenzyl, a stable carbon free radical

✍ Scribed by S. Olivella; M. Ballester; J. Castañer

Book ID
104234608
Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
234 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis

THE formation of perchlorobenzyl (PB) radical has already been postulated in order to account for a number of reactions of perchlorotoluene (I>,l such as its reducto-dimerization to the perchlorostilbenes (II),2 its thermolysis to a mixture of CC14, p erchlorobenzene and perchlorostyrene (III),3'4 and its photolysis in Ccl4 y b ultraviolet light giving a mixture containing perchloroethylbwzene (IV) and other chlorocarbons. 495

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