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Perchloro-9-phenylfluorenyl, a remarkably stable carbon free radical

✍ Scribed by M. Ballester; J. Castañer; J. Pujadas

Book ID
104238768
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
193 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis

THE chemical stability of aryl substituted methyl radicals is the result of a compromise between two main factors: steric hindrance to bonding with the trivalent carbon, and delocalization of the lone electron, the former being the predominant. 192

📜 SIMILAR VOLUMES

Perchlorobenzyl, a stable carbon free ra
Perchlorobenzyl, a stable carbon free radical
✍ S. Olivella; M. Ballester; J. Castañer 📂 Article 📅 1974 🏛 Elsevier Science 🌐 French ⚖ 234 KB

THE formation of perchlorobenzyl (PB) radical has already been postulated in order to account for a number of reactions of perchlorotoluene (I>,l such as its reducto-dimerization to the perchlorostilbenes (II),2 its thermolysis to a mixture of CC14, p erchlorobenzene and perchlorostyrene (III),3'4 a