The title compound, trans-[RhCl(C 18 F 15 P) 2 (CO)], crystallizes with one independent molecule in the asymmetric unit. Important geometric parameters are Rh-P = 2.2797 ( 14) and 2.2993 (14) A ˚, Rh-Cl = 2.3642 (12) A ˚, Rh-C = 1.824 (4) A ˚, C-Rh-Cl = 174.12 (13) , P-Rh-C = 91.73 (13) and 93.71 (1
✦ LIBER ✦
Pentafluorophenyl-phosphorus chemistry—I. Tris(pentafluorophenyl)phosphine sulphide and tris(pentafluorophenyl)dichlorophosphorane
✍ Scribed by H.J. Emeléus; J.M. Miller
- Book ID
- 118906211
- Publisher
- Elsevier Science
- Year
- 1966
- Weight
- 260 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-1902
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Molecules of the title compound, [Rh(C 9 H 6 NO)(C 18 F 15 P)-(CO)], pack in a tail-to-tail fashion, with an intermolecular ligand-to-ligandstacking distance of 3.399 (8) A ˚. The effective cone angle (Â E ) for the phosphine ligand is 163 . The bite angle of the bidentate oxine ligand is 80.77 (10)