𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Pd(0)Cu(I) cocatalyzed coupling of methylphenylphosphine-borane with aryl halides and aryl nonaflates

✍ Scribed by Mohammad Al-Masum; Tom Livinghouse

Book ID
104262414
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
193 KB
Volume
40
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

The reaction of Ph(Me)PH'BH3 with atyl halides in the presence of catalytic Pd(OAc)~JPlhPMe and CuI using ~Pr2NEt as a base in THF at 0 °C furnished the corresponding coupling products in moderate to high yields. A (2-iodophenyl)oxazoline derivative furnished 70% phospholylated coupling product. Phenyl nonaflate underwent coupling with LiCl as an additive.

📜 SIMILAR VOLUMES

ChemInform Abstract: Pd(0)-Mediated Coup
ChemInform Abstract: Pd(0)-Mediated Couplings of Aryl Nonaflates and Triflates with Diphenylphosphine-Borane. Preparation of BH3-Stabilized, Unsymmetrical Triarylphosphines.
✍ Bruce H. Lipshutz; D. J. Buzard; Chol Steve Yun 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

1999 organo-phosphorus compounds, isocyclic C derivatives organo-phosphorus compounds, isocyclic C derivatives S 0084 16 -176 Pd(0)-Mediated Couplings of Aryl Nonaflates and Triflates with Diphenylphosphine-Borane. Preparation of BH 3 -Stabilized, Unsymmetrical Triarylphosphines. -Aryl nonaflates u

ChemInform Abstract: Ligand-Free Fe—Cu C
ChemInform Abstract: Ligand-Free Fe—Cu Cocatalyzed Cross-Coupling of Terminal Alkynes with Aryl Halides.
✍ Niranjan Panda; Ashis Kumar Jena; Sasmita Mohapatra 📂 Article 📅 2012 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

## Abstract The heterogeneous magnetic catalytic system for the C—C cross‐coupling of alkynes (I) with aryl halides (II) and (IV) exploits the synergistic effects of iron and copper in copper ferrite nanoparticles for the alkynylation reaction.

Palladium/Copper (I) halide-cocatalyzed
Palladium/Copper (I) halide-cocatalyzed stereospecific coupling of 1-fluorovinylstannanes with aryl iodides and acyl chlorides
✍ Chen Chen; Keith Wilcoxen; Kyung-il Kim; James R. McCarthy 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 221 KB

Cross-coupling of 1-fluorovinylstannanes with aryl iodides or acyl chlorides, cocatalyzed by palladium and copper (I) iodide proceeded under mild conditions to give substituted fluoro oleflns and ot-fluoro-ct,~-unsaturated ketones, respectively, in good yields with retention of configuration.