Palladium/Copper (I) halide-cocatalyzed stereospecific coupling of 1-fluorovinylstannanes with aryl iodides and acyl chlorides
โ Scribed by Chen Chen; Keith Wilcoxen; Kyung-il Kim; James R. McCarthy
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 221 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Cross-coupling of 1-fluorovinylstannanes with aryl iodides or acyl chlorides, cocatalyzed by palladium and copper (I) iodide proceeded under mild conditions to give substituted fluoro oleflns and ot-fluoro-ct,~-unsaturated ketones, respectively, in good yields with retention of configuration.
๐ SIMILAR VOLUMES
Palladium/copper (I) halide catalyzed cross couplings of (E)-and (Z)-I,2difluorovinyistannanes with aryl iodides and vinyl halides proceeded at room temperature to stereospecifically give 1,2-disubstituted-l,2-difluoroolef'ms and 1,2difluoro or 1,2,3,4-tetrafluorosubstituted dienes in good to excell
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